Publications

2025


212. Assessing Coordination of Organic π-Acceptors to Alkali-Metal Nickelates

L. Vedani, E. Hevia

Chimia, 2025, 79, 869.

https://www.chimia.ch/chimia/article/view/2025_869/2025_869


211. Highly-Reduced Alkali-Metal Nickelates: Synthesis, Structure, Catalytic Applications and Alkali-Metal Effects

L. Vedani, A. M. Borys, K. Rachuy, R. Herbst-Irmer, D. Stalke, E. Hevia

J. Am. Chem. Soc. 2025, 147, 46101

https://pubs.acs.org/doi/abs/10.1021/jacs.5c14047


210. Upgrading Sodium-Mediated Deprotonative Borylation to Catalytic Regimes: Regioselective Control and Mechanistic Implications

C. Tan, A. Tortajada, A. McGinley, M. Mu, Max García-Melchor, E. Hevia

J. Am. Chem. Soc. 2025, 147, 42076.

https://doi.org/10.1021/jacs.5c15994


209. Assessing Sodium Amide Reagents for Ester Amidations in Deep Eutectic Solvents in Continuous Flow

A. W. J. Platten, B. Pinho, L. Torrente-Murciano. E. Hevia

ACS Sustainable Chem. Eng. 2025, 13, 44, 19351

https://doi.org/10.1021/acssuschemeng.5c08775


208. Are Grignard Reactions in Deep Eutectic Solvents Interface-Driven?

I. Manasi, M. Bortoli, D. T. Bowron, M. Campana, O. S. Hammond, T. F. Headen, J. Hooton, E. Hevia, M. Cascella, O. Eisenstein, K. J. Edler

Angew. Chem. Int. Ed. 2025, 64, e202513649

https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202513649


207. Synthesis and Structure of Neopentyl Sodium: A Hydrocarbon-Soluble Reagent for Controlled Sodiation of Non-Activated Substrates

D. E. Anderson, L. Malaspina, S. Grabowsky, E. Hevia

Angew. Chem. Int. Ed. 2025, 64, e202511492

https://onlinelibrary.wiley.com/doi/full/10.1002/anie.202511492


206. Structurally Mapping Sodium-mediated Synthesis of 1,4-substituted dihydropyridines: Nucleophilic Addition vs Deprotonative Metalation

D. Sanchez Roa , J. Kocher , A. Tortajada , E. Hevia

Synthesis, 2025, 57, 3283

https://www.thieme-connect.de/products/ejournals/abstract/10.1055/a-2651-2367


205. Structural and Mechanistic Insights into the Metalation of Fluoroarenes Mediated by a Superbasic Co(II) Bis(amide) Complex

N. Jin, E. Hevia

Chimia, 2025, 79, 224

https://www.chimia.ch/chimia/article/view/2025_224/2025_224


204. Magnesium Nickelate Complexes and Their Implications in Ni-Catalyzed Cross-Couplings of Aryl Fluorides and Aryl Ethers with Grignard Reagents

L. Vedani, A. M. Borys, E. Hevia

Inorg. Chem. 2025, 64, 16, 8354

https://pubs.acs.org/doi/10.1021/acs.inorgchem.5c00755


203. Iron-catalysed direct coupling of organosodium compounds

I. Takahashi, A.Tortajada, D. E. Anderson, L. Ilies, E. Hevia, S. Asako

Nat. Synth. 2025, 4, 816

https://www.nature.com/articles/s44160-025-00771-1


202. Biphenylene Coordination and Ring-Opening by Alkali-Metal Nickelates

A. M. Borys, A. E. F. Denjean, L. Vedani, D. Balcells, E. Hevia

Angew, Chem. Int. Ed. 2025, 64, e202501995

https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202501995


201. Harnessing Organopotassium Reagents for Cross-Coupling with YPhos-Pd Catalysts: Opportunities, Applications, and Challenges

D. Knyszek, J.Löffler, D. E. Anderson, E. Hevia, V. H. Gessner

J. Am. Chem. Soc. 2025, 147, 5417. 

https://pubs.acs.org/doi/full/10.1021/jacs.4c18073


200. Selective Hydrogen Isotope Exchange Catalysed by Simple Alkali-Metal Bases in DMSO

M. S. Tschopp, A. Tortajada, E. Hevia

Angew, Chem. Int. Ed. 2025, 64, e202421736

https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202421736


199. Harnessing Deep Eutectic Solvents for Regioselective Polar Additions to α,β-Unsaturated Ketones and Aldehydes 

A. W. J. Platten, I. Manasi, M. Campana, K. J. Edler, E. Hevia

ChemSusChem 2025, 18, e202402083

https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202402083


198. Structural and Reactivity Implications of Homo and Heterobimetallic Co(II) Amides Prepared via Trans(amination) Reactions

N. Jin, A. Logallo, E. Hevia

Organometalllics, 2025, 4, 197

https://pubs.acs.org/doi/abs/10.1021/acs.organomet.4c00425


197. Room Temperature Intermolecular Hydroamination of Vinylarenes Catalyzed by Alkali-Metal Ferrate Complexes

A. Tortajada, E. Hevia

ACS Org. Inorg. Au, 2025, 5, 62

https://pubs.acs.org/doi/full/10.1021/acsorginorgau.4c00066

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