Hevia Group - Publications

2016

 

99. Structural and Magnetic Diversity in Alkali-Metal Manganate Chemistry: Evaluating Donor and Alkali-Metal

      Effects in Co-complexation Processes

        M. Uzelac, I. Borilovic, M. Amores, T. Cadenbach, A. R. Kennedy, G. Aromí, and E. Hevia

     Chem. Eur. J. 2016, early view

     DOI: 10.1002/chem.201504956

 

98.    Assessing the reactivity of sodium alkyl-magnesiates towards quinoxaline:single elctron transfer

       (SET) vs. nucleophilic alkylation processes

       Z. Livingstone, A. Hernán-Gómez, S. E. Baillie, D. R. Armstrong, L. M. Carrella, W. Clegg,

       R. W. Harrington, A. R. Kennedy, E. Rentschler and E. Hevia 

       Dalton Trans., 2016, Advance Article

       DOI: 10.1039/C5DT04044B 

 

2015

 

97.    Alkali-Metal-Mediated Magnesiations of an N-Heterocyclic Carbene: Normal, Abnormal, and

    “Paranormal” Reactivity in a Single Tritopic Molecule

    A. Martínez-Martínez, M. A. Fuentes, A. Hernán-Gómez, E. Hevia, A. R. Kennedy, R. E. Mulvey,

    C.T.O'Hara

    Angew. Chem. Int. Ed. 2015, 54, 14075

    DOI: 10.1002/anie.201507586 

 

96.    Reactivity of Polar Organometallic Compounds in Unconventional Reaction Media: Challenges and

    Opportunities

    J. Garcia-Alvarez, E. Hevia, V. Capriati

    Eur. J. Org. Chem. 2015, 6779.

    DOI: 10.1002/ejoc.201590088 

 

95.    Accessing Sodium Ferrate Complexes Containing Neutral and Anionic N-Heterocyclic Carbene

    Ligands:

    Structural, Synthetic, and Magnetic Insights

    L. C. H. Maddock, T. Cadenbach, A. R. Kennedy, I. Borilovic, G. Aromí, E. Hevia

    Inorg. Chem. 2015, 54, 9201.

    DOI:  10.1021/acs.inorgchem.5b01638

 

94.    Rational synthesis of normal, abnormal and anionic NHC–gallium alkyl complexes: structural,

    stability and isomerization insights

    M. Uzelac, A. Hernán-Gómez, D. R. Armstrong, A. R. Kennedy, E. Hevia

    Chem. Sci. 2015, 6, 5719.

    DOI: 10.1039/C5SC02086G  

 

93.    Zincate-Mediated Arylation Reactions of Acridine: Pre- and Postarylation Structural Insights

    A. Hernan-Gomez, E. Herd, M. Uzelac, T. Cadenbach, A. R. Kennedy, I. Borilovic, G. Aromi, E. Hevia

    Organometallics, 2015, 34, 2614.

    DOI: 10.1021/om501251q

 

92.    Structurally Defined Zincated and Aluminated Complexes of Ferrocene Made by Alkali-Metal

    Synergistic Syntheses

    W. Clegg, E. Crosbie, S. H. Dale-Black, E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey, D. L

    Ramsay, S. D. Robertson

    Organometallics, 2015, 34, 2580.

    DOI: 10.1021/om5012352 

 

91.        Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural

    and solution implications

    A. J. Roberts, W. Clegg, A. R. Kennedy, M. Probert, S. D. Robertson, E. Hevia

    Dalton Trans. 2015, 44, 8169.

    DOI: 10.1039/C5DT00312A  

 

2014

 

90.    Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition

    of Organolithium and Grignard Reagents to Ketones in Air

    C. Vidal, J. Garcia-Alvarez, A. Hernan-Gomez, A. R. Kennedy, E. Hevia

    Angew. Chem. Int. Ed. 2014, 53, 5969.

    DOI: 10.1002/anie.201400889

 

89.    Potassium-alkyl magnesiates: synthesis, structures and Mg-H exchange applications of aromatic

    and heterocyclic substrates

    S. E. Baillie, T. Bluemke, W. Clegg, A. R. Kenedy, J. Klett, L. Russo, M. de Tullio, E. Hevia,

    Chem. Commun. 2014, 50, 12859.

    DOI: 10.1039/C4CC05305B 

 

88.    New supramolecular assemblies in heterobimetallic chemistry: synthesis of a homologous series of

    unsolvated alkali-metal zincates

    D. R. Armstrong, H. S. Emerson, A. Hernan-Gomez, A. R. Kennedy, E. Hevia

    Dalton Trans. 2014, 43, 14229.

    DOI: 10.1039/C4DT01131G

 

87.        Structural and reactivity insights in Mg Zn hybrid chemistry: Zn-I exchange and Pd-catalysed

    cross-coupling applications of aromatic substrates

    T. D. Bluemke, W. Clegg, P. Garcia-Alvarez, K. Koszinowski, M. D. Call, L. Russo, E. Hevia,

    Chem. Sci. 2014, 5, 3552.

    DOI: 10.1039/C4SC01263A

 

86.    TMP (2,2,6,6-tetramethylpiperidide)-aluminate bases: lithium-mediated alumination or lithiation

    alkylaluminium-trapping reagents?

    D. R. Armstrong, E. Crosbie, E. Hevia, R. E. Mulvey, D. L. Ramsay, S. D. Robertson

    Chem. Sci. 2014, 5, 3031.

    DOI: 10.1039/C4SC01108B

 

85.    Organozinc Pivalate Reagents: Segregation, Solubility, Stabilization, and Structural Insights,

    A. Hernan-Gomez, E. Herd, E. Hevia, A. R. Kennedy, P. Knochel, K. Koszinowski, S.M. Manolikakes,

    R. E. Mulvey, C. Schnegelsberg

    Angew. Chem. Int. Ed. 2014, 53, 2706.

    DOI: 10.1002/anie.201309841

 

84.    Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky

    bis(amido) ligand: deprotomagnesiation reactions of nitrogen-based aromatic substrates

    D. R. Armstrong, W. Clegg, A. Hernan-Gomez, A. R. Kennedy, Z. Livingstone, S. D. Robertson, L. Russo,

    E. Hevia

    Dalton Trans, 2014, 43, 4361 (Invited contribution to themed issue New Talent: Europe)

    DOI: 10.1039/C3DT52639A 

 

2013

 

83.    Donor-Activated Lithiation and Sodiation of Trifluoromethylbenzene: Structural, Spectroscopic,

    and Theoretical Insights

    J. A. Garden, D. R. Armstrong, W. Clegg, J. Garcia-Alvarez, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. D.

    Robertson, L. Russo

    Organometallics, 2013, 32, 5481.

    DOI: 10.1021/om4007664 

 

82.    Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene(NHC) chemistry: Zn–H

    exchange reactions and structural authentication of a dinuclear Au(I) complex with a NHC anion

    D. R. Armstrong, S. E. Baillie, V. L. Blair, N. G. Chabloz, J. Diez, J. Garcia-Alvarez, A. R. Kennedy,

    S. D. Robertson, E. Hevia

    Chem. Sci. 2013, 4, 4259.

    DOI: 10.1039/C3SC52101J 

 

81.    Concealed Cyclotrimeric Polymorph of Lithium 2,2,6,6-Tetramethylpiperidide Unconcealed: X-Ray

    Crystallographic and NMR Spectroscopic Studies

    E. Hevia, A. R. Kennedy, R. E. Mulvey, D. L. Ramsay, S. D. Robertson

    Chem. Eur. J. 2013, 19, 14069.

    DOI: 10.1002/chem.201302709 

 

80.    Developing Catalytic Applications of Cooperative Bimetallics: Competitive Hydroamination

    Trimerization Reactions of Isocyanates Catalysed by Sodium Magnesiates

    A. Hernán-Gómez, T. D. Bradley, A. R. Kennedy, Z. Livingstone, S. D. Robertson, E. Hevia,

    Chem. Commun. 2013, 49, 8659.

    DOI: 10.1039/C3CC45167D 

 

79.    Isomeric and chemical consequences of the direct magnesiation of 1,3-benzoazoles using

    diketiminate-stabilized magnesium bases

    S. E. Baillie, V. L. Blair, T. Bradley, W. Clegg, J. Cowan, R. Harrington, A.  Hernan-Gomez, A. R. Kennedy,

    Z. Livingstone, E. Hevia

    Chem. Sci. 2013, 4, 1895.

    DOI: 10.1039/C3SC22326D 

 

78.        Co-complexation Syntheses, Structural Characterization, and DFT studies of a novel series of

    Polymeric Alkali-Metal Tetraorganogallates

    D. R. Armstrong, E. Brammer, T. Cadenbach, E. Hevia, A. R. Kennedy

    Organometallics, 2013, 32, 480.

    DOI: 10.1021/om3009469

 

2012

 

77.        Synthesis, structural elucidation, and diffusion-ordered NMR studies of homoleptic alkyllithium

    magnesiates: donor-controlled structural variations in mixed-metal chemistry

    S. D. Baillie, W. Clegg, P. Garcia-Alvarez, E. Hevia, A. R. Kennedy, J. Klett, L. Russo

    Organometallics, 2012, 31, 5131-5142.

    DOI: 10.1021/om300477m

 

76.    Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its

    coordinative repertoire

    T. Cadenbach, E. Hevia, A. R. Kenendy, R. E. Mulvey, J. A. Pickrell, S. D. Robertson

    Dalton Transactions, 2012, 41,10141-10144.

    DOI: 10.1039/C2DT31061A

 

75.        New Lithium-Zincate Approaches for the Selective Functionalisation of Pyrazine: Direct

    Dideprotozincation vs Nucleophilic Alkylation

    S. E. Baillie, V. L. Blair, D. C. Blakemore, D. Hay, E. Hevia, A. R. Kenendy, D. C. Pryde

    Chem. Commun. 2012, 48, 1985-1987.

    DOI: 10.1039/C2CC16959B 

 

74.    Assessing the reactivity of sodium zincate [(TMEDA)Na(TMP)ZntBu2] towards benzoylferrocene:

    deprotonative metalation vs alkylation reactions

    E. Hevia, A. R. Kennedy, M. D. McCall

    Dalton Trans 2012, 41, 98-103

    DOI: 10.1039/C1DT11465D 

 

2011

 

73.        Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated-zincation with

    indirect sodiation-dialkylzinc co-complexation

    D. R. Armstrong, L. Balloch, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, S. D. Robertson

    Belstein J. Org. Chem. 2011, 7, 1234-1248.

    DOI: 10.3762/bjoc.7.144

 

72.        Magnesium-Mediated Benzothiazole Activation: a Room Temperature Cascade of C-H

    Deprotonation, C-C Coupling, Ring-Opening and Nucleophilic Addition Reactions

    V. L. Blair, W. Clegg, A. R. Kennedy, Z. Livingstone, L. Russo, E. Hevia

    Angew. Chem. Int. Ed. 2011, 50, 9857-9860.

    DOI: 10.1002/ange.201103275 

 

71.        A record-breaking Magnesium-Hydride Molecular Cluster: Implications for hydrogen storage

    E. Hevia, R. E.Mulvey

    Angew. Chem. Int. Ed. 2011, 50, 9242-9243.

    DOI: 10.1002/anie.201102978

 

70.    Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

    E. Hevia, R. E. Mulvey

    Angew. Chem. Int. Ed. 2011, 50, 6448-6450.     DOI: 10.1002/anie.201102054 

 

69.    Alkali-metal mediated zincation of N-heterocyclic substrates using the lithium zincate complex,

    (THF)Li(TMP)Zn(tBu)2 and applications in in situ cross-coupling reactions

    V. L. Blair, D. C. Blakemore, D. Hay, E. Hevia, D. C. Pryde

    Tet. Lett. 2011, 52, 4590-4594.

    DOI: 10.1016/j.tetlet.2011.06.090

 

68.    A New Polymeric alkyl/alkoxide magnesium-sodium inverse crown complex

    S. E. Baillie, V. L. Blair, E. Hevia, A. R. Kennedy

    Act Cryst., 2011, C67, m249-m251.

    DOI: 10.1107/S0108270111023134 

 

67.    Expanding Mg-Zn hybrid chemistry: Inorganic salt effects in addition reactions of organozinc

    reagents to trifluoromethyl acetophenone and implications for a synergistic lithium-magnesium-zinc

    activation

    D. R. Armstrong, W. Clegg, P. García-Alvarez, M. D. McCall, A. R. Kennedy, L. Russo, E. Hevia

    Chem. Eur. J, 2011 17, 8333-8341.

    DOI: 10.1002/chem.201100866 

 

66.    Shedding New Light on ZnCl2-Mediated Addition Reactions of Grignard Reagents to Ketones:

    Structural Authentication of Key Intermediates and Diffusion-Ordered NMR Studies

    D. R. Armstrong, W. Clegg, P. García-Alvarez, E. Hevia, M. D. McCall, L. Nuttall, A. R. Kennedy, L. Russo

    Chem. Eur. J, 2011, 17, 4470.

    DOI: 10.1002/chem.201002544 

 

65.    Synthesis and Characterization of an Infinite Sheet of Metal-Alkyl Bonds: Unfolding the Elusive     Structure of an     Unsolvated Alkali-Metal Trisalkylmagnesiate

    S. E. Baillie, W. Clegg, P. Garcia-Alvarez, E. Hevia, A. R. Kennedy, J. Klett, L. Russo

    Chem. Commun, 2011, 47, 388-390.

    DOI: 10.1039/C0CC02164D

 

2010

 

64.    Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of

    Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

    D. R. Armstrong,.V. L. Blair, W. Clegg, S. H. Dale, J. García-Alvarez, E. Hevia, G. W. Honeyman,

    R. E. Mulvey, L. Russo

    J. Am. Chem. Soc. 2010, 132, 9480-9487.

    DOI: 10.1021/ja1038598 

 

63.    Exposing the Hidden Complexity of Stoichiometric and Catalytic Metathesis Reactions by  

    Elucidation of Mg-Zn Hybrids

    J. Z. Chua, P. García-Álvarez, E. Hevia, A. R. Kennedy, M. D. McCall

    Proc. Natl. Acad. Sci. USA, 2010, 107, 5294-5299.

    DOI: 10.1073/pnas.0913307107

 

62.    New Insights into Addition Reactions of Dialkylzinc Reagents to Trifluoromethyl Ketones:

    Structural Authentication of a -hydride Elimination Product Containing a Tetranuclear Zinc Chain

    E. Hevia, A. R. Kennedy, J. Klett, Z. Livingstone, M. D. McCall

    Dalton Trans, 2010, 39, 520-526.

    DOI: 10.1039/B911818G

 

2009

 

61.    Closer Insight into the Reactivity of TMP-dialkyl Zincates in Directed ortho-Zincation of Anisole:

    Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

    W. Clegg, B. Conway, E. Hevia, M. D. McCall, L. Russo, R. E. Mulvey

    J. Am. Chem. Soc. 2009, 131, 2375-2384.

    DOI: 10.1021/ja8087168

 

60.    Donor-dictated Interlocking Co-complexation Reactions of LiNHDipp with Dimethylzinc: Synthesis

    and Structures of New Methyl(amido)zincates

    W. Clegg, D. V. Graham, E. Herd, E. Hevia, A. R. Kennedy, M. D. McCall, L. Russo

    Inorg. Chem. 2009, 48, 5320-5327.

    DOI: 10.1021/ic900313b 

 

59.    Direct lateral Metallation using Alkali-Metal-Mediated Zincation (AMMZn): SiC-H vs Si-O Bond

    Cleavage

    E. Hevia, A. R. Kennedy, J. Klett, M. D. McCall

    Chem. Commun. 2009, 3240-3242.

    DOI: 10.1039/B903592C

 

58.    Synthetic and Structural Insights into the Zincation of Toluene: Direct Synergic Ring Metalation vs

    Indirect Non-synergic Lateral Metalation

    D. R. Armstrong, J. García-Álvarez, D. V. Graham, G. W. Honeyman, E. Hevia, A. R. Kennedy,

    R. E. Mulvey

    Chem. Eur. J, 2009, 15, 3800-3807.

    DOI: 10.1002/chem.200801928

 

57.        Contacted ion-pair lithium alkylamidoaluminates: intramolecular alumination (Al-H exchange)

    traps for TMEDA and PMDETA

    B. Conway, J. García-Álvarez, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. D. Robertson

    Organometallics, 2009, 28, 6462-6468.

    DOI: 10.1021/om900736a

 

56.    Synergic Synthesis of Benzannulated Zincabicyclic Complexes, -Zincated N Ylides, through Sodium

    TMEDA-Mediated Zincation of a Haloarene

    D. R. Armstrong, L. Balloch, W. Clegg, S. H. Dale, P. García-Álvarez, E. Hevia, L. M. Hogg, A. R. Kennedy,

    R. E. Mulvey, C. T. O’Hara

    Angew. Chem. Int. Ed. 2009, 48, 8675-8678.

    DOI: 10.1002/anie.200904506 

 

55.        Structurally Defined Potassium-Mediated Zincation of Pyridine and 4-R-Substituted Pyridines (R=

    Et, iPr, tBu, Ph and Me2N) by Using Dialkyl-TMP-Zincate Bases

    W. Clegg, B. Conway, D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey, L. Russo, D. S. Wright

    Chem. Eur. J. 2009, 15, 7074-7082.

    DOI: 10.1002/chem.200900549 

 

2008

 

54.    Synthesis and Structural Elucidation of Alkyl, Amido and Mixed Alkyl-Amido “Highly-Coordinated”

    Zincates

    D. R. Armstrong, C. Dougan, D. V. Graham, E. Hevia, A. R. Kennedy

    Organometallics, 2008, 27, 6063-6070.

    DOI: 10.1021/om800786n

 

53.        Metalation of 2, 4, 6-Trimethylacetophenone using Organozinc Reagents

    D. R. Armstrong, A. M. Drummond, L. Balloch, D. V. Graham, E. Hevia, A. R. Kennedy

    Organometallics, 2008, 27, 5860-5866.

    DOI: 10.1021/om800658s

 

52.    Synthesis and Structural Elucidation of Solvent-Free and Solvated Lithium Dimethyl(HMDS)

    zincates

    D. R. Armstrong, E. Herd, D.V. Graham, E. Hevia,  A. R. Kennedy, W. Clegg, L. Russo

    Dalton Trans. 2008, 1323-1330.

    DOI: 10.1039/B716494G 

 

51.        Transamination Chemistry of Sodium TMP-zincate: Synthesis and Crystal Structure of a Chiral

    Amidozincate

    D. R. Armstrong, W. Clegg, S. H. Dale, J. García-Álvarez, R. W. Harrington, E. Hevia, G. W. Honeyman,

    A. R. Kennedy, R. E. Mulvey, C. T. O’Hara

    Chem. Commun. 2008, 187-189.

    DOI: 10.1039/B713987J 

 

50.    Unmasking Representative Structures of TMP-Active Hauser and Turbo Hauser Bases

    P. García-Álvarez, D. V. Graham, E. Hevia, A. R. Kennedy, J. Klett, R. E. Mulvey, C. T. O’Hara,

    S. Weatherstone

    Angew. Chem. Int. Ed. 2008, 47, 8079-8081.

    DOI: 10.1002/anie.200802618 

 

49.    Synthesis, Structural Authentication, and Structurally Defined Metalation Reactions of Lithium and

    Sodium DA-Zincate Bases (DA= diisopropylamide) with Phenylacetylene

    W. Clegg, J. García-Álvarez, P. García-Álvarez, D. V. Graham, R. W. Harrington, E. Hevia, A. R. Kennedy,

    R. E. Mulvey, L. Russo

    Organometallics. 2008, 27, 2654-2663.

    DOI: 10.1021/om8001813

 

48.    Structurally-defined Potassium-Mediated Regioselective Zincation of Amino-and Alkoxy

    Substituted Pyridines

    B. Conway, D. V. Graham, E. Hevia, A. R. Kennedy, J. Klett, R. E. Mulvey

    Chem. Commun. 2008, 2638-2640.

    DOI: 10.1039/B805606D 

 

47.    Synthesis and Characterisation of New Bimetallic Alkali Metal-Magnesium Mixed

    Diisopropylamide-Acetylides: Structural Variations in Bimetallic Lithium- and Sodium-Heteroleptic

    Magnesiates

    J. García-Álvarez, D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey

    Dalton Trans. 2008, 1481-1486.

    DOI: 10.1039/B716215D 

 

46.    Alkali-Metal-Mediated Manganation(II) of Functionalized Arenes and Applications of

    Ortho-Manganated Products in Pd-Catalyzed Cross-Coupling Reactions with Iodobenzene

    V. L. Blair, W. Clegg, B. Conway, E. Hevia, A. Kennedy, J. Klett, R. E. Mulvey, L. Russo

    Chem. Eur. J. 2008, 14, 65-72.

    DOI: 10.1002/chem.200701597

 

45.    Structurally-Defined Reactions of Sodium TMP-Zincate with Nitrile Compounds:  Synthesis of a

    Salt-like Sodium Sodiumdizincate and Other Unexpected Ion Pair Products

    W. Clegg, S. H. Dale, E. Hevia, L. M. Hogg, G. W. Honeyman, R. E. Mulvey, C. T. O’Hara, L. Russo

    Angew. Chem. Int. Ed. 2008, 47, 731-734.

    DOI: 10.1002/anie.200704341

 

2007

 

44.    Structurally-Defined Direct C-Magnesiation and C-Zincation of N-Heterocyclic Aromatic

    Compounds     using Alkali-Metal-Mediated Metallation

    B. Conway, E. Hevia, A. R. Kennedy, R. E. Mulvey

    Chem. Commun. 2007, 2864-2866.

    DOI: 10.1039/B704362G 

 

43.    Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for

    dismutation phenomena in TMP-alumination chemistry

    B. Conway, E. Hevia, J. García-Álvarez, D. V. Graham, A. R. Kennedy, R. E. Mulvey

    Chem. Commun. 2007, 5241-5243.

    DOI: 10.1039/B713913F 

 

42.    Lewis base stabilized lithium TMP – aluminates: an unexpected fragmentation and capture reaction

    involving cyclic ether 1,4-dioxane

    J. Garcia-Alvarez, E. Hevia, A. R. Kennedy, J. Klett, R. E. Mulvey

    Chem. Commun. 2007, 2402-2404.

    DOI: 10.1039/B700785J

 

41.        Synthesis of Mixed Alkali Metal-Zinc Enolate Complexes Derived from 2, 4, 6-

    Trimethylacetophenone: New Inverse Crown Structures

    S. H. Baillie, E. Hevia, A. R. Kennedy, R. E. Mulvey

    Organometallics, 2007, 26, 204-209.

    DOI: 10.1021/om060878k 

 

40.    Structural Variations in Bimetallic Sodium-Magnesium and Sodium-Zinc Ketimides, and a Sodium-

    Zinc Alkide-Alkoxide-Amide: Connections to Ring-Stacking, Ring-Laddering, and Inverse Crown

    Concepts

    W. Clegg, S. H. Dale, D. V. Graham, R. W. Harrington, E. Hevia, L. M. Hogg, A. R. Kennedy, R. E. Mulvey

    Chem. Commun. 2007, 1641-1643.

    DOI: 10.1039/B618609B    

 

39.    Dizincation and Dimagnesiation of Benzene using Alkali-Metal-Mediated Metallation

    D. R. Armstrong, W. Clegg, S. H. Dale, D. V. Graham, E. Hevia, L. M. Hogg, G. W. Honeyman,

    A. R. Kennedy, R. E. Mulvey

    Chem. Commun. 2007, 598-600.

    DOI: 10.1039/B613655A    

 

2006

 

38.    Lithium Dimethyl-amidozinc Complexes: Contrasting Zincate (Amido = TMP) and Inverse Zincate

    (Amido = HMDS) Structures on Addition of TMEDA

    D. V. Graham, E. Hevia, A.R. Kennedy, R. E. Mulvey

    Organometallics, 2006, 25, 3297-3300.

    DOI: 10.1021/om060334i

 

37.        Synthesis and Reactivity of New(Methoxy)methyl Complexes of Manganese(I) and Rhenium(I)

    E. Hevia, D. Miguel, J. Pérez, V. Riera

    Organometallics, 2006, 25, 4909-4912.

    DOI: 10.1021/om060459n

 

36.    Synergic Para-Directed-Monometalation of Bis(toluene)chromium by using Alkali-Metal-Mediated

    Magnesiation

    P. C. Andrikopoulos, D. R. Armstrong, E. Hevia, A. R. Kennedy, R. E. Mulvey

    Organometallics, 2006, 25, 2415-2418.

    DOI: 10.1021/om060216v 

 

35.        Synthesis and Characterization of New Mixed-Metal Sodium-Magnesium Enolates Derived from 2,

    4, 6-Trimethylacetophenone

    E. Hevia, K. W. Henderson, A. R. Kennedy, R. E. Mulvey

    Organometallics, 2006, 25, 1778-1785.

    DOI: 10.1021/om051076c 

 

34.    Electronic Structure and Excited States of Rhenium(I) Amido and Phosphido Carbonyl-Bipyridine

    Complexes Studied by Picosecond Time-Resolved IR Spectroscopy and DFT Calculations

    A. Grabrielsson, M. Busby, P. Matousek, MI. Towrie, E. Hevia, L. Cuesta, J. Perez, S. Zalis, A. Vlcek, Jr

    Inorg. Chem. 2006, 45, 9789-9797.

    DOI: 10.1021/ic0614768

 

33.        Alkali-Metal-Mediated Zincation of Polycyclic Aromatic Hydrocarbons: Synthesis and Structures

    of Monozincated and Dizincated Naphthalenes

    W. Clegg, S. H. Dale, E. Hevia, L. M: Hogg, G. W. Honeyman, R. E. Mulvey, C. T. O´Hara

    Angew. Chem. Int. Ed. 2006, 45, 6548-6550.

    DOI: 10.1002/anie.200602288

 

32.    Alkali-Metal-Mediated Zincation of Anisole: Synthesis and Structures of Three Instructive

    Ortho-Zincated Complexes

    W. Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, R. E. Mulvey

    J. Am. Chem. Soc. 2006, 128, 7434-7435.

    DOI: 10.1021/ja061898g

 

31.        Directed Meta-Metalation Using Alkali-Metal-Mediated Zincation

    D. R. Armstrong, W. Clegg, S. H. Dale, E. Hevia, L. M. Hogg, G. W. Honeyman, R. E. Mulvey

    Angew. Chem. Int. Ed. 2006, 45, 3775-3778.

    DOI: 10.1002/anie.200600720

 

30.    Reactivity of Molybdenum and Rhenium Hydroxo Complexes toward Organic Electrophiles:

    Reactions that Afford Carboxylato Products

    L. Cuesta, E. Hevia, D. Morales, J. Pérez, L. Riera, D. Miguel

    Organometallics, 2006, 25, 1717-1722.

    DOI: 10.1021/om051081g

 

29.    Pre-Metalation Insights into the Use of Alkali-Metal-Mediated Zincation for Directed ortho

    Metalation of a Tertiary Aromatic Amide

    W. Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, R. E. Mulvey

    Angew. Chem. Int. Ed. 2006, 45, 2370-2374.

    DOI: 10.1002/anie.200503202

 

28.    Post-Metalation Insights into the Use of Alkali-Metal-Mediated Zincation for Directed ortho-

    Metalation of a Tertiary Aromatic Amide

    W. Clegg, S. H. Dale, R. W. Harrington, E. Hevia, G. W. Honeyman, R. E. Mulvey

    Angew. Chem. Int. Ed. 2006, 45, 2374-2377.

    DOI: 10.1002/anie.200503213

 

27.        Building an Extended Inverse Crown Motif via Alkali-Metal-Mediated -Magnesation of Furan

    D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, Christine Talmard

    Chem. Commun. 2006, 417.

    DOI: 10.1039/B514985A 

 

2005

 

26.    Trapping, Stabilization, and Characterization of an Enolate Anion of a 1, 6 – Adduct of

    Benzophenone Chelated by a Sodium Alkylamidozincate Cation

    E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey

    J. Am. Chem. Soc. 2005, 127, 13106-13107.

    DOI: 10.1021/ja053756c

 

25.    Alkali-Metal–Mediated Zincation of Ferrocene: Synthesis, Structure, and Reactivity of a New

    Lithium TMP-Zincate Reagent

    H. R. L. Barley, William Clegg, S. H. Dale, E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey

    Angew. Chem. Int. Ed., 2005, 44, 6018-6021.

    DOI: 10.1002/anie.200501560

 

24.    Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions

    P. C. Andrikopoulos, D. R. Armstrong, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara

    Chem. Commun. 2005, 1131-1133.

    DOI: 10.1039/B416636A

 

23.    Sodium Dialkyl-amidozincates, Alkyl or Amido Bases? An Experimental and Theoretical Case Study

    P. C. Andrikopoulos, D. R. Armstrong, H. R. L. Barley, W. Clegg, S. H. Dale, E. Hevia, G. W. Honeyman,

    A. R. Kennedy, R. E. Mulvey

    J. Am. Chem. Soc. 2005, 127, 6184-6186.

    DOI: 10.1021/ja050860l

 

22.    Selective Meta-Deprotonation of Toluene Using Alkali Metal-Mediated Magnesiation.

    P. C. Andrikopoulos, D. R. Armstrong, D. V. Graham, E. Hevia, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara,

    C. Talmard

    Angew. Chem. Int. Ed. 2005, 44, 3459-3462.

    DOI: 10.1002/anie.200500379 

 

21.        Synthesis and characterization of a series of alkylmagnesium amide and related oxygen-

    contaminated alkoxy compounds

    B. Conway, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. Weatherstone

    Dalton Trans. 2005, 1532-1544.

    DOI: 10.1039/B501502B 

 

20.    Activation of ancillary ligands in the reactions of DMAD with phosphido and alkylidenamido

    rhenium complexes

    L. Cuesta, E. Hevia, D. Morales, J. Pérez, V. Riera, M. Seitz, D. Miguel

    Organometallics 2005, 24, 1772-1775.

    DOI: 10.1021/om049019r

 

19.        Activation of a 1,10-phenanthroline ligand on a rhenium tricarbonyl complex

    L. Cuesta, E. Hevia, D. Morales, J. Pérez, V. Riera, E. Rodríguez, D. Miguel

    Chem. Commun. 2005, 116-117.

    DOI: 10.1039/B412447B 

 

18.        Synergic monodeprotonation of bis(benzene)chromium using mixed alkali metal-magnesium

    amide bases and structural characterization of the heterotrimetallic products

    E. Hevia, G. W. Honeyman, A. R. Kennedy, R. E. Mulvey, D. C. Sherrington

    Angew. Chem. Int. Ed. 2005, 44, 68-72.

    DOI: 10.1002/anie.200460637 

 

2004

 

17.        Isolation and characterization of the heterometallic sodium-magnesium mixed monoalkyl-

    bisamido complex [Na(-Bu)(-TMP)Mg(TMP).(TMEDA)]: chelate-trapping of a surprising intermediate

    in the formation of  inverse crowns

    E. Hevia, D. J. Gallagher, A. R. Kennedy, R. E. Mulvey, C. T. O’Hara, C. Talmard

    Chem. Commun. 2004, 2422-2423.

    DOI: 10.1039/B410293B 

 

16.    A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse

    crown ring compounds synthesized via mixed sodium-magnesium tris(diisopropylamide) synergic     base

    P. C. Andrikopoulos, D.  R. Armstrong, W. Clegg, C. J. Gilfillan, E. Hevia, A. R. Kennedy, R. E. Mulvey,

    C. T.     O’Hara, J.  A. Parkinson, D. M. Tooke

    J. Am. Chem. Soc. 2004, 126, 11612-11620.

    DOI: 10.1021/ja0472230 

 

15.        Synthesis and crystal structure of [{nBuMg(-TMP)2}] and of a homometallic inverse crown in

    tetranuclear [{nBuMg2[-N(H)Dipp]2(3-OnBu)}2]

    E. Hevia, A. R. Kennedy, R. E. Mulvey, S. Weatherstone

    Angew. Chem. Chem. Int. Ed. 2004, 43, 1709-1712.

    DOI: 10.1002/anie.200353286

 

14.        Reactivity of Molybdenum and Rhenium hydroxo-carbonyl complexes toward organic

    electrophiles

    L. Cuesta, D. C. Gerbino, E. Hevia,  D. Morales, M. E. Navarro Clemente, J. Pérez, L. Riera, V. Riera,

    D. Miguel, I. Del Rio, S. Garcia-Granda

    Chem. Eur. J. 2004, 10, 1765-1777.

    DOI: 10.1002/chem.200305577

 

2003

 

13.        Solvent-free and TMEDA-solvated mixed alkali metal-magnesium tris-diisopropylamides

    E. Hevia, F. R. Kenley, A. R. Kennedy, R. E. Mulvey, R. B. Rowlings

    Eur. J. Inorg. Chem. 2003, 3347-3353.

    DOI:  10.1002/ejic.200300413 

 

12.        Synthesis of -lactams from a N-rhenaimine: effect of the transition metal on the energetic profile

    of the Staudinger reaction

    E. Hevia, J. Pérez, V. Riera, D. Miguel, M. I. Menéndez, T. L. Sordo, S. García-Granda

    J. Am. Chem. Soc. 2003, 125, 3706-3707.

    DOI: 10.1021/ja034070s

 

11.        Mono and dimetallic cyanocomplexes with {Mo(3-allyl)(CO)2(N-N)} fragments

    J. Pérez, E. Hevia, L. Riera, V. Riera, S. García-Granda, E. García-Rodríguez, D. Miguel

    Eur. J. Inorg. Chem. 2003, 1113-1120.

    DOI: 10.1002/ejic.200390142

 

10.    A new reactivity pattern of low-valent transition-metal hydroxo complexes: straightforward

    synthesis of hydrosulfido complexes via reaction with carbon disulfide

    D. Gerbino, E. Hevia, D. Morales, M. E. Navarro Clemente, J. Pérez, L. Riera, V. Riera, D. Miguel

    Chem. Commun. 2003, 328-329.

    DOI: 10.1039/B210860G

 

9.        Reactivity of the amido complex [Re(NHpTol)(CO)3(bipy)] toward neutral organic electrophiles

    E. Hevia, J. Pérez, V. Riera, D. Miguel

    Organometallics 2003, 22, 257-263.

    DOI: 10.1021/om020667p

 

2002

 

8.        Manganese (I) and rhenium (I) tricarbonyl (alkylthio)methyl and alkylidenesulfonium complexes

    E. Hevia, J. Pérez, V. Riera, D. Miguel

    Organometallics 2002, 21, 5312-5319.

    DOI: 10.1021/om020522i 

 

7.        Insertion and cycloaddition reactivity of a transition-metal N-metalloimine

    E. Hevia, J. Pérez, V. Riera, D. Miguel

    Angew. Chem. Int. Ed. 2002, 41, 3858-3860.

    DOI: 10.1002/1521-3773

 

6.        Insertion of Unsaturated Organic Electrophiles into Molybdenum-Alkoxide and Rhenium-

    Alkoxide Bonds of Neutral, Stable Carbonyl Complexes

    E. Hevia, J. Pérez, L. Riera,  V. Riera, I. Del Río, S. García-Granda, D. Miguel

    Chem. Eur. J. 2002, 8, 4510-4521.

    DOI: 10.1002/1521-3765

 

5.        Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)3(bipy)] (R = H or

    Me): N-H vs. Re-N

    E. Hevia, J. Pérez, V. Riera, D. Miguel

    Chem. Comun. 2002, 1814-1815.

    DOI: 10.1039/B203261A  

 

4.        New synthetic routes to cationic rhenium tricarbonyl bipyridine complexes with labile ligands

    E. Hevia, J. Pérez, V. Riera, D. Miguel, S. Kassel, A. Rheingold

    Inorg. Chem. 2002, 41, 4673-4679.

    DOI: 10.1021/ic020174c  

 

3.        New octahedral rhenium (I) tricarbonyl amido complexes

    E. Hevia, J. Pérez,  V. Riera, D. Miguel

    Organometallics 2002, 21, 1966-1974.

    DOI: 10.1021/om0110383

 

2.        Reactive Alkoxide Complexes of Groups 6 and 7 Metals

    E. Hevia, J. Pérez, L. Riera, V. Riera, D. Miguel

    Organometallics 2002, 21, 1750-1752.

    DOI: 10.1021/om010977s 

 

2001

 

1.        Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of

    phosphorus oxoanions

    L. T. Burke, E. Hevia-Freire, R. Holland, J. C. Jeffery, A. P. Leedham, C. A. Russell, A. Steiner, A. Zagorski

    Chem. Comun. 2000, 1769-1770.

    DOI: 10.1039/B004192K

Eva Hevia Group, Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde,

295 Cathedral Street, Glasgow, G1 1XL, UK